Oligoepoxides with side epoxy-groups are synthsized and studied. Using data of elemental and functional, IR and NMR spectral analyses the composition and structure of the synthesized oligomers have been established. The perspective application of synthesized oligomers for manufacturing of oligo-aminoalcohols by their interaction with seeral heterocyclic amines has been showed. Possible spheres of their application have been determined as well.